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CAS RN: 87413-09-0 | Product Number: D2045
Dess-Martin Periodinane
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Purity: >95.0%(T)
Synonyms:
- 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one
- DMP
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
€43.00
|
3 | 4 |
|
| 5G |
€93.00
|
15 | 30 |
|
| 25G |
€233.00
|
14 | 13 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
Supplemental Product Information:
This product may generate a little insoluble matter overtime while storing.
Since no effect the reaction, please filtering as needed before use.
| Product Number | D2045 |
| Purity / Analysis Method | >95.0%(T) |
| Molecular Formula / Molecular Weight | C__1__3H__1__3IO__8 = 424.14 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Frozen (-20°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive,Moisture Sensitive,Heat Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 87413-09-0 |
| Reaxys Registry Number | 4548207 |
| PubChem Substance ID | 87568496 |
| Merck Index (14) | 2933 |
| MDL Number | MFCD00130127 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(Iodometric Titration) | min. 95.0 % |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 124 °C(dec.) |
| Solubility (soluble in) | Chloroform, Acetone |
| Solubility (slightly sol. in) | Ether |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H341 : Suspected of causing genetic defects. H272 : May intensify fire; oxidizer. |
| Precautionary Statements | P220 : Keep away from clothing and other combustible materials. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P201 : Obtain special instructions before use. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. |
Related Laws:
Transport Information:
| UN Number | UN1479 |
| Class | 5.1 |
| Packing Group | III |
| HS Number | 2934999090 |
Application
TCI Practical Example: Mild Oxidation Using Dess-Martin Periodinane
Used Chemicals
Procedure
To dichloromethane (10 mL) was added trans-2-phenyl-1-cyclohexanol (0.30 g，1.7 mmol) and DMP (0.72 g, 1.7 mmol) at room temperature. The reaction mixture was stirred overnight at room temperature, then diluted with diethyl ether and washed with saturated aqueous sodium bicarbonate, 10% aqueous sodium thiosulfate, water and brine. The organic layer was concentrated under reduced pressure. The resulting crude product was purified by column chromatography (hexane:ethyl acetate = 8:1 on silica gel) to give 1 as a white solid (0.22 g, 74% yield).
Experimenter’s Comments
The reaction mixtures were monitored by TLC (hexane:ethyl acetate = 4:1).
Analytical Data（2-Phenylcyclohexanone (1)）
1H NMR (400 MHz, CDCl3); δ 7.37-7.31 (m, 2H), 7.30-7.22 (m, 1H), 7.17-7.12 (m, 2H), 3.62 (dd, 1H, J = 12.4, 6.9 Hz), 2.58-2.41 (m, 2H), 2.33-2.23 (m, 1H), 2.22-2.10 (m, 1H), 2.10-1.94 (m, 2H), 1.91-1.75 (m, 2H).
13C NMR (101 MHz, CDCl3); δ 210.5, 138.9, 128.6, 128.5, 127.0, 57.5, 42.3, 35.2, 27.9, 25.5.
Lead Reference
- Acceleration of the Dess-Martin Oxidation by Water
Application
Dess-Martin Periodinane Reagent
References
- M. Horikawa, K. Hashimoto, H. Shirahama, Tetrahedron Lett. 1993, 34, 331.
- J. N. Haseltine, M. P. Cabal, N. B. Mantlo, N. Iwasawa, D. S. Yamashita, R. S. Coleman, S. J. Danishefsky, G. K. Schulte, J. Am. Chem. Soc. 1991, 113, 3850.
- J. P. Burkhart, N. P. Peet, P. Bey, Tetrahedron Lett. 1988, 29, 3433.
- D. B. Dess, J. C. Martin, J. Org. Chem. 1983, 48, 4155.
- R. J. Linderman, D. M. Graves, Tetrahedron Lett. 1987, 28, 4259.
PubMed Literature
Articles/Brochures
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Safety Data Sheet (SDS)
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Specifications
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Other Documents
Related Products
Dess-Martin Periodinane (8-12% in Dichloromethane)
| Product # | D4477 |
| CAS RN | 87413-09-0 |
| Purity / Analysis Method: |