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CAS RN: 1375325-71-5 | Product Number: C2734
Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)
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![Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)")
Purity: >98.0%(T)
Synonyms:
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
244,00 €
|
1 | ≥40 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | C2734 |
| Purity / Analysis Method | >98.0%(T) |
| Molecular Formula / Molecular Weight | C__2__4H__3__7ClNPPd = 512.41 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| CAS RN | 1375325-71-5 |
| Reaxys Registry Number | 22750896 |
| PubChem Substance ID | 253659744 |
| MDL Number | MFCD21608496 |
Specifications
| Appearance | Light yellow to Amber to Dark green powder to crystal |
| Purity(Chelometric Titration) | min. 98.0 % |
Properties (reference)
| Melting Point | 159 °C(dec.) |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
Transport Information:
| HS Number | 2843909000 |
Application
Palladium Complex Catalyzing Cross Coupling Reactions with Activating C-H Bond of Polyfluoroarenes
Experimental procedure: In a glovebox, to a vial containing bromobenzene (62 mg, 0.4 mmol), 1 (10.0 mg, 0.02 mmol), pivalic acid (20 mg, 0.2 mmol), K3PO4 (168 mg, 0.8 mmol) and DMA (1 mL) is added pentafluorobenzene (98 mg, 0.6 mmol). After stirring at 80 °C for 2-4 h, the reaction is quenched by the addition of NH4Cl solution. The product is extracted with ethyl acetate (3 x 15 mL) and the combined organic layer is washed with brine and dried with Na2SO4. After removal of solvents under vacuum, the crude product is purified by column chromatography (silica gel; hexanes) to give the corresponding product as a colorless oil (86% yield).
References
- tBu3P-Coordinated 2-Phenylaniline-Based Palladacycle Complexes as Precatalyst for Pd-Catalyzed Coupling Reactions of Aryl Halides with Polyfluoroarenes by a C–H Activation Strategy
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